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Cl2 / ClO2 sensor

Chlorine / Chlorine dioxide

Reliable real-time
data on Cl2 / ClO2

GasPlug TECHNOLOGY | PATENTED DESIGN

Chlorine/Chlorine Dioxide (Cl2/ClO2) Smart Cartridge - Kunak
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Where are they found?

Chlorine (Cl2) is a greenish-yellow gas with a strong, irritating odour. It is highly reactive and classified as a toxic gas. Cl2 is not flammable, but it is an oxidising agent, meaning it can intensify fires when in contact with combustible materials.

Chlorine dioxide (ClO2) is a reddish-yellow gas with a pungent chlorine-like odour. It is a strong oxidising agent. Though effective in microbial control, it is also a toxic air pollutant and regulated due to its potential health and environmental impacts.

Neither Cl2 nor ClO2 are naturally present, but they are widely present in industrial processes. Their presence in the environment is mainly due to human activity, in paper and textile industry, waste water treatment plants (WWTP) and in chemical manufacturing.

Why are they harmful?

Both Cl2 and CLO2 are highly toxic and pose serious health and environmental hazards.

Their Inhalation can cause severe irritation of the respiratory tract, coughing, and pulmonary edema, while contact with the skin or eyes leads to painful burns and tissue damage. Chronic exposure may result in long-term respiratory conditions.

Environmentally, they are extremely harmful to aquatic organisms.

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Cl2 / ClO2 cartridge

The Cl2 / ClO2 cartridge has a built-in electrochemical sensor capable of measuring both Cl2 and ClO2 pollutants, from low concentrations (ppb level) to high concentrations. The cartridge is calibrated against Cl2, while the response to ClO2 is higher than 70%.

This dual cartridge is an excellent option for measuring chlorine compounds when co-existing in the same applications (WWTP, disinfection applications, etc.), offering high stability, fast response and recovery, and robustness to environmental performance, being an excellent cartridge for industrial monitoring.

Technical specifications

Type
Electrochemical
Unit of measurement
mg/m3, ppm
Measurement range(1)
0-20 ppm
Resolution(2)
1 ppb
Operating temperature range(3)
-20 to 50ºC
Operating RH range(4)
0 to 99 %RH
Recommended RH range(5)
15 to 90 %RH
Operating life(6)
> 24 months
Guarantee range(7)
250 ppm
Limit of Detection (LOD)(8)
2 ppb
Repeatability(9)
Response time(10)
< 60 sec
Typical accuracy(12)
±20 ppb
Typical Intra-model variability(14)
< 3 ppb
  1. Measurement range: concentration range measured by the sensor.
  2. Resolution: smallest unit of measurement that can be indicated by the sensor.
  3. Operating temperature range: temperature interval at which the sensor is rated to operate safely and provide measurements. (**) In PM sensor Type A: -40 to 50ºC with heater (more information on this version on request).
  4. Operating RH range: humidity interval at which the sensor is rated to operate safely and provide measurements.
  5. Recommended RH range: Recommended relative humidity range for optimal sensor performance. Continuous exposure outside the recommended range may damage the cartridge.
  6. Operating life: time period during which the sensor can operate effectively and accurately under normal conditions.
  7. Guarantee range: concentration range covered by Kunak's guarantee.
  8. LOD (Limit Of Detection): measured at laboratory conditions at 20ºC and 50% RH. The limit of detection is the minimum concentration that can be detected as significantly different at zero gas concentration, calculated according to the Technical Specification CEN/TS 17660.
  9. Repeatability: measured at laboratory conditions at 20ºC and 50% RH. Closeness of the agreement between the results of successive measurements of the same measure carried out under the same conditions of measurement, calculated according to the Technical Specification CEN/TS 17660.
  10. Response time: time needed by the sensor to reach 90% of the final stable value.
  11. Typical precision - R2: statistics obtained between the device hourly measurements and reference instruments in field test between -10 to +30ºC at different locations. (*) For the type B PM sensor, the expected error for PM10 is higher in presence of coarse particles.
  12. Typical accuracy: for criteria pollutants is the average Mean Absolute Error (MAE) obtained between the device hourly measurements and reference instruments for 1 to 8 months field test between -10 to +30ºC in different countries. For other pollutants is the expected error of the measurement at the reading.
  13. DQO-Typical U(exp): Data Quality Objetive expresed as the Expanded Uncertainity in the Limit Value obtained between the device hourly measurements and reference instruments for 1 to 8 months field test between -10 to +30ºC in different countries, calculated according to the European Air Quality Directive 2024/2881 and from the Technical Specification CEN/TS 17660. (*) For the type B PM sensor, the expected error for PM10 is higher in presence of coarse particles.
  14. Typical intra-model variability: calculated as the standard deviation of the three sensor means in 1 to 8 months field test between -10 to +30ºC in different countries.

A, B, C, D superindex: the super indexes refer to different types of cartridges related to the same target pollutant but with different technical specifications.

It is essential to have an instrument that is capable of accurately measuring pollution levels and providing reliable results to make informed decisions on air quality and public health.

Javier Fernández

CEO & Co-founder - Kunak